ISSN 1008-5548

CN 37-1316/TU

Journal Online  2018 Vol.24
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Synthesis and supercapacitor properties of ZnFe2O4 nanoparticles-graphene composites

HAN Zhenzhen, JIA Huimin, YANG Shuhua, CAO Bingqiang, JIANG Yanan

(School of Material Science and Engineering, University of Jinan, Jinan 250022, China)

Abstract:In order to improve the electrochemical properties of ZnFe2O4, a simple and low-cost one-step solvothermal method for synthesizing ZnFe2O4 nanoparticles-graphene composites was designed. The composites were characterized by X ray diffraction, scanning electron microscopy and transmission electron microscopy, and analysised by electrochemical workstation. The results show that the method not only prevents the agglomeration of two-dimensional layered graphene, but also controls the size of ZnFe2O4 particles at the nanoscale and uniformly adheres to the graphene sheet. The specific surface area can reach up to 180 m2/g and the number of active sites were increased effectively due to the two-dimensional layered structure and the exceedingly good conductivity of grapheme. The specific capacitance of ZnFe2O4 nanoparticles-graphene composites electrode reaches 180.9 F/g when the current density is 1 A/g, indicating the better electrochemical performance than the pure ZnFe2O4 electrode.

Keywords: ZnFe2O4; nanoparticles; graphene; supercapacitor

中图分类号:TQ139.2           文献标志码:A

文章编号:1008-5548(2018)01-0086-04

DOI:10.13732/j.issn.1008-5548.2018.01.016

收稿日期:2017-10-13, 修回日期:2017-10-31,在线出版时间:2018-02-25。

基金项目:国家自然科学基金项目,编号:51472110,51702123;山东省自然科学基金项目,编号:ZR2017ZB0316。

第一作者简介:韩臻臻(1987—),女,硕士研究生,研究方向为新能源材料与器件。E-mail:1447209005@qq.com。

通信作者简介:

曹丙强(1978—),男,博士,教授,博士生导师,研究方向为新能源材料与器件。E-mail:mse_caobq@ujn.edu.cn。

杨树华(1986—),男,博士,讲师,研究方向为新能源材料与器件。E-mail:yangshuhua78@163.com。