ISSN 1008-5548

CN 37-1316/TU

Journal Online  2018 Vol.24
<Go BackNo.3

Properties of modified coal gangue power plant ash filled polypropylene composite materials

SUN Zhiming, GUO Yongchang, DUAN Yongwei, DU Yuansheng, WU Cuiping, ZHENG Shuilin

(College of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China)

Abstract:Ultra-fine coal gangue power plant ash was modified with different surface modification agent, and blended with polypropylene (PP) . Ash-PP composite material was obtained by extrusion and injection molding, and its mechanical properties were also measured. The effects of modified ash on the mechanical properties and crystallization behavior of composite materials were studied by the SEM, FT-IR and DSC. The results show that the modification effect of silane coupling agent SCA1113 and SCA 503 are optimal. The tensile strength, the bending strength, and the impact strength increase from 25.70 to 29.58 MPa, 33.60 to 35.99 MPa, and 3.04 to 3.85 k J·m-2 respectively. The modified ash in the composite plays an important role in the polypropylene because of heterogeneous nucleation effect, to increase the crystallization temperature of polypropylene and the crystallization rate, and decrease the crystallite size distribution.

Keywords:gangue power plant; ash; polypropylene; silane coupling agent; mechanical property

中图分类号:TQ327             文献标志码:A

文章编号:1008-5548(2018)03-0001-05

DOI:10.13732/j.issn.1008-5548.2018.03.001

收稿日期:2018-01-25, 修回日期:2018-03-20,在线出版时间:2018-05-08。

基金项目:固废资源化利用与节能建材国家重点实验室开放课题项目,编号:SWR-2014-004。

第一作者简介:孙志明(1986—),男,博士,副教授。研究方向为非金属矿物材料。E-mail: 13466774499@163.com。

通信作者简介:郑水林(1956—),男,博士,教授,博士生导师,研究方向为矿物材料。E-mail:13601339820@163.com。