ZUO Cheng, WU Man, GUO Qingjie
(Key Laboratory of Clean Chemical Processing of Shandong Province, School of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract:This paper summarizes the progress of dehydrogenation of light alkanes to light olefins, which includs the catalysts and technologies of anaerobic and aerobic dehydrogenation. The chemical looping technology, a method of dehydrogenate of light alkanes to light olefins is proposed. In the chemical looping technology, the oxygen carriers as mild oxidants were applied to the oxidative dehydrogenation of light carbon alkanes to light olefins, which could increase the light alkanes conversion rate of reaction. It is pointed out that the researches on the dehydrogenation of light alkanes to olefins mainly include two sections: The oxygen carrier should be focused on the followingthree aspects: multiple active oxygen carrier, coupled catalytic oxygen carrier oxygen carrier and weak oxidizing oxygen carrier;For the bottleneck of slow reaction between oxygen carrier and light alkane, the design idea of the reactor should be optimized.
Keywords:chemical-looping technology; light alkanes; light olefins; oxygen carrier; reactor
文章编号:1008-5548(2018)05-0053-08
DOI:10.13732/j.issn.1008-5548.2018.05.009
收稿日期:2018-03-09, 修回日期:2018-06-01,在线出版时间:2018-10-16。
基金项目:山东省自然科学基金重点项目,编号:ZR2015QZ02;山东省重点研发计划项目,编号:2016GSF117005。
第一作者简介:左成(1989—),男,博士研究生,研究方向为化学反应工程。E-mail:17854270427@163.com。
通信作者简介:郭庆杰(1967—),男,博士,教授,博士生导师,研究方向为流态化工程、能源环境工程。E-mail:qj_guo@yahoo.com。