ISSN 1008-5548

CN 37-1316/TU

Journal Online  2017 Vol.23
<Go BackNo.2

Preparation and characterization of magnetic Fe3O4@SiO2 composite particles

XU Longfei, ZHANG Zhili, LI Decai, ZHANG Haiming, YANG Yang

(School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China)

Abstract:Fe3O4 magnetic particles prepared by chemical coprecipitation and tetraethoxysilane hydrolysis method were coated with SiO2. The prepared particles were characterized by X ray diffractometer, contact angle measuring instrument, vibrating sample magnetometer and transmission electron microscopy and so on. The results show that the surface of the magnetic particles is coated with a layer of SiO2, the size of the coated particles is about 20 nm with superparamagnetic property.The contact angle decreases from 120 to 90°, and the lipophilicity is significantly enhanced. The saturation magnetization of the composite Fe3O4 particles decreases with the increase of the coating amount of SiO2, its value is 84 kA/m, which can meet the application requirements.

Keywords: magnetic particles Fe3O4; morphous SiO2; superparamagnetic; Fe3O4@SiO2 composite particles

中图分类号:TB34         文献标志码:A

文章编号:1008-5548(2017)02-0084-04

DOI:10.13732/j.issn.1008-5548.2017.02.017

收稿日期:2016-05-19,修回日期:2016-09-21,在线出版时间:2017-04-26。

基金项目:国家自然科学基金,编号 :61271049;教育部创新团队发展计划,编号:IRT13046;北京交通大学人才基金项目,编号:M14RC0040。

第一作者简介:许龙飞(1989—),男,硕士研究生,研究方向为磁性液体理论及应用。E-mail:12121371@bjtu.edu.cn。

通信作者简介:张志力(1966—),女,博士,教授,博士生导师,研究方向为磁性液体理论及应用。E-mail:zlzhang@bjtu.edu.cn。