QIN Haiqing, LIU Wenping, LEI Xiaoxu, LIN Feng, ZHANG Zhenjun, ZHANG Jianwei
(a. National Engineering Research Center for Special Mineral Material; b. Guangxi Key Laboratory of Superhard Material, China Nonferrous Metal (Guilin) Geology and Mining Co., Ltd. Guilin 541004, China)
Abstract:Si nano-powders were prepared by radio frequency inductively coupled plasma evaporation method, which were good crystalline and smooth surface spherical powders. Specific surface area and average grain diameter were 40.03 m2/g and 64.05 nm respectively. 10% Si nano-powders dispersion liquid with ethylene glycol and deionized water wsa prepared. It can be found that Si nano-powders in ethylene glycol has better dispersion and smaller particle size than in deionized water, particle size distribution is94.17152.88 nm. Silicon carbon composite cathode materials at m (G) : m (Si) ratio have better electrochemical performance, which are prepared through pulping with 10% Si nano-powers ethylene glycol dispersion and graphite. First discharge capacity is812.5mA·h/g, charge capacity is 631.0 mA·h/g, and capacity remain is 73.74% after 30 cycles.
Keywords: Si nano-powders; dispersion; composite anodes; electrochemical properties
文章编号:1008-5548(2017)04-0088-06
DOI:10.13732/j.issn.1008-5548.2017.04.018
收稿日期:2016-09-22,修回日期:2017-06-19,在线出版时间:2017-08-25。
基金项目:桂林市科技攻关项目,编号:2016010706;桂林市“1020”创新驱动计划重大攻关项目,编号:20160204;中国有色集团科技计划项目,编号:2016KJJH03
第一作者简介:秦海青(1979—),男,硕士,高级工程师,研究方向为新能源材料、纳米金属粉体的制备及应用。Email:qinhaiqing5218@163.com。
通信作者简介:刘文平(1986—),男,硕士,工程师,研究方向为新能源材料、纳米金属粉体的制备及应用。Email:092101207@163.com。