ISSN 1008-5548

CN 37-1316/TU

Journal Online  2017 Vol.23
<Go BackNo.6

Study on hydropobic modification of superfine ammonium poly-phosphate

LI Xiaopan, YAN Shuyuan, HE Yongjun, LIANG Yaodong

(Department of Chemistry Engineering, Xi’an University of Science and Technology, Xi’an 710054, China)

Abstract:Methyl hydrogen polysiloxane fluid was used as modifier, activated clay as catalyst, talcum powder, mica powder and hydrophobic silica as accessories, by the detection of hydrophobic retention, moisture content, hygroscopicity and fluidity, the effect of methylhydrosilicone fluid, hydrophobic silica addition time and adding method, modification temperature, talc powder and mica powder on the modification of superfine ammonium polyphosphate were studied. The results show that when the amount of methyl hydrogen containing silicone oil is 12 g, the hydrophobicity retention rate of modified superfine ammonium polyphosphate is 94.5%. The stirring rate should be followed by first increase after the decrease and then increase. After methyl hydrogen polysiloxane fluid cross-linking polymerization, hydrophobic silica must be added at once.Modified temperature includes the dispersion temperature55~60 ℃, film temperature 100~105 ℃. Compared with the traditional fire extinguishing material ammonium dihydrogen phosphate modification process, the activated clay do not change the hydrophobicity of the material.

Keywords:superfine ammonium poly-phosphate; methylhydro silicone fluid; hydophobic modification

中图分类号:TQ06          文献标志码:A

文章编号:1008-5548(2017)06-0090-06

DOI:10.13732/j.issn.1008-5548.2017.06.017

收稿日期:2017-01-19, 修回日期:2017-09-23,在线出版时间:2017-12-25。

基金项目:公安部消防局科技项目,编号:2012XFCX09。

第一作者简介:李晓攀(1991—),男,硕士研究生,研究方向为粉体改性研究。E-mail :lixiaopan610323@163.com。

通信作者简介:贺拥军(1967—),男,博士,教授,硕(博)士生导师,研究方向为粉体材料研究。E-mail :yongjunhe@xustedu.cn。