JU Wei, YI Xibin, ZHANG Jing, WANG Qichun, MU Qiuhong, FAN Huili
(New Material Institute, Key Lab for Adhesion & Sealing Materials of Shandong Province,Shandong Academy of Sciences, Jinan 250014, China)
Abstract:The flake silver powders were prepared by planetary ball milling, and then characterized by scanning electron microscopy(SEM) and thermogravimetric analyzer(TGA).Based on the characterization results, the impacting factors on fabrication and treatment of flake silver were studied. With the conditions that spherical powder as precursor, zirconia balls as balls, ethanol as milling media, milling speed with 200 r/min, the mass ratio of ball and powder with 12:1, the mass ratio of media and powder with 2:1, fill factor with 0.5, and oleic acid as milling aids, the high flaky silver powder with different particle size is prepared with the increase of milling time. After being treated, the surface of silver particle is rough, and TGA is less than 0.1%. The result shows that the flake silver powder achieves the application standard.
Keywords: flake silver powder; kinetic energy of milling; ball; milling speed; flaky rate
文章编号:1008-5548(2016)06-0046-04
DOI:10.13732/j.issn.1008-5548.2016.06.011
收稿日期:2016-04-06,修回日期:2016-11-08,在线出版时间:2016-12-06。
基金项目:山东省中青年科学家科研奖励基金项目,编号:BS2011CL036;山东省自然科学基金,编号:ZR2015YL002。
第一作者简介:琚伟(1981—),男,博士,助理研究员,研究方向为贵金属材料。E-mail:quwei8175@126.com。
通信作者简介:伊希斌(1981—),男,博士,副研究员,研究方向为无机纳米材料。E-mail:yixb@sdas.org。