ISSN 1008-5548

CN 37-1316/TU

Journal Online  2015 Vol.21
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Effect of Reaction Temperature on Morphology of Calcium Carbonate Nano-particles Prepared from Carbide Slags

XIE Nanjie1 , CAO Jianxin2a , GAO Chuanping2b , LIN Qian2a

(1. Guizhou Chemical Construction Corporation, Guiyang 550018,China; 2. a. Guizhou Key Laboratory for Green Chemical and Clean Energy Technology; b. Guizhou Key Laboratory for Efficient Utilization of Mineral and Green Chemical Technology, Guizhou University,Guiyang 550025, China)

Abstract:To improve the added values of carbide slags, the effect of reaction temperature on the morphology of calcium carbonate nano-particles prepared from carbide slags without crystal controlling agents was investigated. The results show that the calcite nano-particles with flake and spherical morphologies can be prepared when the reaction temperatures are 3 and 8 ℃. The vaterite and aragonite nano-particles can be prepared at the reaction temperature of 10 and 80 ℃. The average sizes of the calcium carbonate nano-particles with spherical, quasi-spherical and needle morphologies are respectively 90, 70 and 80 nm.

Keywords: reaction temperature; carbide slag; morphology; calcium carbonate nano-particles

中图分类号:X781.2,TQ09         文献标志码:A

文章编号:1008-5548(2015)01-0022-05

DOI:10.13732/j.issn.1008-5548.2015.01.005

收稿日期:2014-05-05, 修回日期:2014-06-13,在线出版时间:2015-03-02。

基金项目:国家科技部支撑计划项目,编号:2007BAE10B01;贵州省科技计划资助项目,编号:黔科合重大专字 2006-6033。

第一作者简介:偰南杰(1962—),男,工程师,研究方向为氯碱化工及过程节能减排技术。 E-mail:gzxienanjie@163.com。

通信作者简介:林倩(1962—),女,博士,教授,博士生导师,研究方向为绿色化工技术。 E-mail:celinqian@126.com。