ISSN 1008-5548

CN 37-1316/TU

Journal Online  2014 Vol.20
<Go BackNo.4

Preparation and Gas Sensing Property of Peony-like Submicrometer Cupric Oxide Particles

CHEN Cheng1, YAO Xiaoting1, ZHU Yongheng1, ZHU Zhigang1, ZHU Haixiang1, 2, WANG Yanxiang2

(1. School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University, Shanghai 201209, China; 2. School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, China)

Abstract: Peony-like submicrometer cupric oxide particles were synthesized by the water bath heating method using copper nitrate as copper source and methenamine as alkali source. The size and morphology of the as-prepared products were characterized by scanning electron microscopy. The gas sensing property of the product were measured by the stationary state gas distribution method. The results indicate that the cupric oxide particles are composed of microstructured triangular nanosheets. The morphology of the cupric oxide particles alters from spindle-like, via butterfly-like, to peony-like microstructure as the concentration of methenamine increases. The cupric oxide particles have better response to hydrogen sulfide.

Keywords: cupric oxide; microstructure; shape control; gas-sensing property

中图分类号:TB383          文献标志码:A

文章编号:1008-5548(2014)04-0017-04

DOI:10.13732/j.issn.1008-5548.2014.04.004

收稿日期:2013-12-24,在线出版时间:2014-08-28。

基金项目:上海高校特聘教授(东方学者)岗位支持计划;上海市科委基础研究重点项目,编号: 13NM1401300;教育部留学回国人员科研启动基金;上海高校青年教师培养资助计划,编号: ZZEGD12001;上海第二工业大学校科研启动基金,编号: EGD13XQD14;上海第二工业大学校级重点学科(第四期)建设,材料学,编号:XXKPY1302。

第一作者简介:陈诚(1983-),男,博士,讲师,研究方向为功能化纳米材料制备与性能。 E-mail:chencheng@sspu.edu.cn。

通信作者简介:朱志刚(1977-),男,教授,研究方向为智能传感材料与器件。 E-mail:zgzhu@sspu.edu.cn。