ISSN 1008-5548

CN 37-1316/TU

Journal Online  2013 Vol.19
<Go BackNo.2

Preparation of Lanthanum Doped γ-Al2O3 Powders by Solution Combustion Method

CHEN Ruirui, CHU Gang, FANG Dong

(School of Chemistry and Materials Science, Liaoning Shihua University,Fushun 113001,China)

Abstract:Lanthanum doped γ-Al2O3powders were prepared by solution combustion methodusingAl(NO3)3.9H2OandLa(NO3)3.6H2Oasoxygenant and C2H5NO2 as reductant.The products were characterized by analysis means of XRD,XPS and TEM.The effects of calcinations time,calcinations temperature and the amount of substance ratio on products were inspected.The results show that the composite products of lanthanum doped γ-Al2O3can be prepared by solution combustion method in one step.Calcination time,calcination temperature and the amount of substance ratio of reactants affect the products in a certain degree.La3+is effective on the thermal stability of the γ-Al2O3 composite powders.The temperature can reach 950 ℃.There is no La2O3 in the products.La3+ can exist in the space of γ-Al2O3crystal,which cannot replace the place of Al3+.

Keywords:solution combustion method;modification;thermal stability

中图分类号:TB35 文献标志码:A

文章编号:1008-5548(2013)02-0044-04

DOI :10.3969/j.issn.1008-5548.2013.02.011

收稿日期:2012-09-29,修回日期:2012-11-26。

基金项目:辽宁省自然科学基金资助项目,编号:201102119。

第一作者简介:陈瑞瑞(1987—),女,硕士研究生,研究方向为无机纳米材料。 E-mail :chenruirui08@163.com。

通信作者:储刚(1963—),男,博士,教授,研究方向为无机非金属材料。电话:13841363058, E-mail :chugang@126.com