ISSN 1008-5548

CN 37-1316/TU

Journal Online  2013 Vol.19
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Surface Hydrophobic Modification of Aluminum Phosphate by Solid-state Method

WANG Qiuru, HUO Jichuan, LEI Yonglin

(School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China)

Abstract:To improve compatibility of aluminum phosphate and organics,the surface hydrophobic modification of aluminum phosphate powders were researched by solid-state method.The properties of aluminum phosphate powders before and after modification as well as the modification mechanism were analyzed by the test means of FTIR,TG and TFSEM.The results indicate that at thermostatic water bath of 80 ℃,the activation index of aluminum phosphate powders is more than 99% after modified by silane coupling agent with the mass fraction of 6%.The static water contact angle is about 130°.After heated at 200 ℃ for 2 h,the modifying method is transformed from physical adsorption to chemical adsorption.The activation index increases to 100% and the static water contact angle reaches 145°.

Keywords:aluminum phosphate;solid-state method;silane coupling agent;surface hydrophobic modification

中图分类号:TQ133.1           文献标志码:A

文章编号:1008-5548(2013)02-0060-05

DOI :10.3969/j.issn.1008-5548.2013.02.015

收稿日期:2012-09-11,修回日期:2012-11-10。

基金项目: 国家高技术研究发展计划 (863 计划) 重点项目, 编号:2009AA035002。

第一作者简介:王秋入(1987—),女,硕士研究生,研究方向为功能复合材料。 电话:15983697319,E-mail: qiuru_wang@163.com。

通信作者:霍冀川(1962—),男,硕士,教授,硕士生导师,研究方向为复合功能材料、 生物质化学和混凝土外加剂。 电话:0816-2419209, E-mail: huojichuan@swust.edu.cn。