ISSN 1008-5548

CN 37-1316/TU

Journal Online  2013 Vol.19
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Form and Mechanism of N Doped TiO2 Nano-particles-Palygorskite Composite Materials

SONG Bing, ZHENG Shuilin, LIU Yue, ZHAGN Yumo, LU Fanghui

(School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China)

Abstract:N doped TiO2nano-particles-palygorskite composite materials were prepared by method of hydrolyze-depositing. UV-Vis spectrometer was applied to characterize the absorption spectra and the band gap of the composite materials. Combining with FTIR and XPS test, the form and mechanism of N-doping were analyzed. The results show that N is doped into the composite materials by the forms of TiN,NHxand NOx. The band gap of the composite materials decreases 0.58 eV. The threshold of absorbable light wavelength is approved by 105.35 nm.

Keywords:TiO2 nano-particle; palygorskite; doping; composite materials; absorption spectrum

中图分类号:N34              文献标志码:A

文章编号:1008-5548(2013)04-0021-03

DOI:10.3969/j.issn.1008-5548.2013.04.006

收稿日期:2013-01-09,修回日期:2013-01-14,在线出版时间:2013-08-25。

第一作者简介: 宋兵(1987—),男,硕士研究生,研究方向为非金属矿深加工。 E-mail:molmolsong@126.com。

通信作者简介: 郑水林(1956—), 男,博士,教授,研究方向为资源综合利用与非金属矿深加工、 粉体制备与表面处理、 非金属矿物材料与环境材料。E-mail: shuilinzh@sina.com。