吴红娥1,2, 费广涛1, 高旭东1, 郭 霄1, 宫欣欣1, 马晓丽1, 王 庆1, 许少辉1
（1. 中国科学院合肥物质科学研究院固体物理研究所, 安徽合肥230031; 2. 安徽工程大学化学与环境工程学院, 安徽芜湖241000）
引用格式：吴红娥, 费广涛, 高旭东, 等. 聚苯胺及其复合材料的制备及应用研究进展[J]. 中国粉体技术, 2023, 29(5): 70-80.WU H E,FEI G T, GAO X D, et al. Research progress on preparation and application of polyaniline and its composite materials[J]. China Powder Science and Technology, 2023, 29(5): 70-80.
DOI：10.13732/j.issn.1008-5548.2023.05.009v
收稿日期：2023-04-29,修回日期：2023-08-17，在线出版时间：2023-08-25 12：03。
基金项目：国家自然科学基金项目,编号:51971210。
第一作者简介：吴红娥(1982—),女,副教授,博士,研究方向为光电材料。E-mail: hongewu@ahpu.edu.cn。
通信作者简介：费广涛(1962—),男,研究员,博士,博士生导师,研究方向为光电材料。E-mail: gtfei@issp.ac.cn。
摘要：针对聚苯胺具有良好的应用前景和商业价值的现状,对聚苯胺及其复合材料的制备方法进行综述,包括化学氧化聚合法、 电化学氧化聚合法、 酶催化聚合法、 乳液聚合法、 原位聚合法和光诱导聚合法等;根据聚苯胺具有较强的导电性能、 优良的环境稳定性、 可调节的氧化态等特点,介绍聚苯胺及其复合材料在吸附材料、 传感器、 超级电容器、 太阳能电池、 电磁屏蔽材料及发光二极管等领域中的应用。指出聚苯胺作为一种重要的导电高分子聚合物,未来的研究重点是通过可控的合成方法与无机半导体粒子形成复合材料,利用聚苯胺的能量传递作用增强无机半导体材料的荧光性能等。
关键词：导电高分子聚合物; 聚苯胺; 复合材料
Abstract：In view of the current situation of polyaniline with good application prospects and commercial value, the preparation methods of polyaniline and its composite materials were reviewed, including chemical oxidative polymerization, electrochemical oxidative polymerization, enzyme-catalyzed polymerization, emulsion polymerization, in-situ polymerization, photo-induced polymerization and so on. According to the characteristics of polyaniline such as strong electrical conductivity, excellent environmental stability and adjustable oxidation state, the applications of polyaniline and its composite materials in the fields of adsorption materials, sensors, supercapacitors, solar cells, electromagnetic shielding materials and light-emitting diodes were introduced. The focus of future research about polyaniline will be to form composites with inorganic semiconductor particles through controllable synthesis methods because of polyaniline as an important conductive polymer. The energy transfer of polyaniline can be used to enhance the fluorescence properties of inorganic semiconductors.
Keywords：conductive polymer; polyaniline; composite materials
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