摘要：通过正交实验并借助于ＸＲＤ 和ＴＥＭ 等手段，研究了前驱物配比、反应温度、反应时间、升温速率等工艺因素对水热合成纳米ZrSiO₄的影响。结果表明：前驱物配比、反应温度、反应时间及升温速率是影响纳米ZrSiO₄ 粉体合成的主要因素，同时，当前驱物m (Zr) ∶ m (Si) =1 2∶1 0 ，反应温度为３３５ ℃，反应时间为４ｈ，升温速率为１－６ ℃／ｍｉｎ 时，可制得晶粒规整、分散性好、粒度在１００ｎｍ 以下的ZrSiO₄ 粉体。

关键词：水热合成;纳米ZrSiO₄;工艺因素;

Abstract：The effects of hydrothermal reaction conditions on synthesis of ZrSiO₄ are studied by orthogonal design m (Zr) ∶ m (Si) of the precursors, reaction temperature, reaction time and rate of rising temperature are primary factors Under the condition of m (Zr) ∶ m (Si) =1 2∶1 0 of the precursors, temperature of 335℃, time of 4h and rate of 1 6℃/min, the ultrafine ZrSiO₄ powders are synthesised by hydrothermal method which are well crystallized, well degree of dispersion and the particle size is less than 100nm

Keyword： hydrothermal synthesis;nanometer ZrSiO₄;technical conditions;