摘要：研究了工业废料电石泥的可利用性,并实现了其向平均粒径约为100nm超微碳酸钙的实用性转化。本文中对比了涡流高剪切法和苛化法制备超微碳酸钙的优劣,并证实前者比后者优越。采用激光粒度分析仪、TEM等手段对颗粒形态与结构进行表征,证实上述方法可靠可行。在上述实验结果的基础上,本文中首次将第四统计力学群子统计理论用于解释碳酸钙的微观结构和剪切速率之间的关系,发现剪切破碎速率对碳酸钙粒径有很大影响。

关键词：电石泥;超微碳酸钙;涡流高剪切法;苛化法;

Abstract: The recycle of calcium carbide residue is studied by the newlyturbo-flow equipment, which is taken into the useful ultra-fine CaCO₃; pow-der with the average particle size less than 100 nm. It is approved that themethodology of turbo-flow is superior to that of basification. The preparedparticles are characterized by laser particle sizes distribution and TEMBasing on above research results ,JRG sub-cluster statistics theory is firstused to explain the relationship between the microstructures of CaCO₃ andthe rate of shear. The rate of shear affects the particle size of CaCO₃.

Key words: calcium carbide residue; ultra-fine calcium carbide; turbo-flow process ; basification