摘要：利用溶胶-凝胶法制备CaCu₃Ti₄O₁₂粉体,采用差热分析、X射线衍射、扫描电子显微镜等技术进行表征,并探讨CaCu₃Ti₄O₁₂粉体的烧结特性及电性能。结果表明,干凝胶经750℃低温煅烧可获得粒径分布较窄、平均粒径为80～100 nm的CaCu₃Ti₄O₁₂粉体。CaCu₃Ti₄O₁₂陶瓷在1 000℃时实现致密烧结,比固相反应法制备的粉体烧结温度降低100～200℃,具有较宽的烧结温区。溶胶-凝胶法制备的陶瓷经1 050℃烧结2 h,获得优良的电性能,相对介电常数为20 190,介电损耗为0.022,非线性系数为4.530。

关键词：溶胶-凝胶法；电性能；物相结构；微观结构

Abstract：CaCu₃Ti₄O₁₂ powders were prepared by sol-gel method and characterized by TG-DTA,XRD and SEM.The sintering characteristics and electric properties of CaCu₃Ti₄O₁₂ powders were investigated.The results show that CaCaCu₃Ti₄O₁₂ powders with a diameter of 80～100 nm and narrow particle size distribution can be obtained by low temperature calcining the xerogel at 750 ℃.CaCu₃Ti₄O₁₂ ceramics made from the powder can be sintered at 1 000 ℃ to acquire the dense structure.The sintering temperature is lower by 100～200 ℃ than the sample obtained by solid reaction method using micron powders.The sintering range of CaCu₃Ti₄O₁₂ ceramics is also widened.At the sintering temperature of 1 050 ℃ for 2 h,CaCu₃Ti₄O₁₂ ceramics made from powder have good electric properties.The relative dielectric constant value is 20 190,loss tangent is 0.022,and nonlinear coefficient is 4.530.

Keywords：sol-gel process；electric properties；phase structure；micro structure