赵一志,沈志刚,张晓静,赵小虎

（北京航空航天大学 a.航空科学与工程学院; b.粉体技术研究开发北京市重点实验室,北京 100191）

DOI：10.13732/j.issn.1008-5548.2021.01.002

收稿日期：2020-08-25，修回日期：2020-10-08，在线出版时间：2020-11-02 10:31。

基金项目：航天科学技术基金项目，编号:BH2020-09。

第一作者简介：赵一志(1991—)，男，博士研究生，研究方向为微纳米材料制备应用。E-mail:xjzhaoyizhi@buaa.edu.cn。

通信作者简介：沈志刚(1958—)，男，博士，教授，博士生导师，研究方向为微纳米材料制备应用与空间环境防护。E-mail:shenzhg@buaa.edu.cn。

摘要：石墨烯薄膜、石墨烯基复合涂料、六方氮化硼、二硫化钼等二维纳米材料具有良好的抗渗透性，在腐蚀防护领域有着广阔的应用前景。首先，概述单层和多层石墨烯涂层的制备方法、防腐机理、实际存在的问题及改进方法;随后，在石墨烯基复合涂料方面，主要探讨石墨烯和氧化石墨烯的各种共价或非共价改性方法及其在有机涂料中的腐蚀防护机制；此外，介绍六方氮化硼和其他二维纳米材料作为新型耐腐蚀材料的主要研究成果；最后，对二维纳米材料在腐蚀防护领域的研究前景进行展望。

关键词：二维纳米材料；腐蚀防护；涂层；薄膜；改性

Abstract：Two-dimensional nano-materials such as graphene films,graphene-based composite coatings,hexagonal boron nitride and molybdenum disulfide have excellent properties of anti-permeability and have broad application prospects in the field of corrosion protection. Firstly,the preparation methods,anticorrosion mechanism,existing problems and improvement methods of single-layer and multi-layer graphene coatings are summarized. Subsequently,in terms of graphene-based composite coatings,various covalent or non-covalent modification methods of graphene and graphene oxide and their corrosion protection mechanisms in organic coatings are mainly discussed. In addition,the main research results of boron nitride and other two-dimensional nanomaterials as new corrosion resistant materials are introduced. Finally,the research prospect of two-dimensional nanomaterials in the field of corrosion protection is prospected.

Keywords：two-dimensional nano-materials; corrosion protection; coating; film; modification

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