ISSN 1008-5548

CN 37-1316/TU

2022年28卷  第1期
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粉磨方式对粉煤灰理化特性的影响

Influence of grinding method on physicochemical properties of fly ash

杨烨霖,廖洪强,段思宇,王建科


DOI:10.13732/j.issn.1008-5548.2022.01.006

收稿日期: 2021-05-18,修回日期:2021-11-03,在线出版时间:2021-12-02。

基金项目:国家重点研发计划项目,编号:2020YFB0606204;山西省重点研发计划项目,编号:201903D31007;山东省重大科技创新工程项目,编号:2019JZZY020306。

第一作者简介:杨烨霖(1995—),男,硕士研究生,研究方向为固体废弃物资源化利用。E-mail:smile12579@163.com。

通信作者简介:廖洪强(1966—),男,教授,博士,博士生导师,研究方向为固体废弃物资源化利用。E-mail:liaohongq@sxu.edu.cn。


摘要:为提升粉煤灰综合利用效率,采用球磨机和蒸汽动能磨对粉煤灰进行粉磨,对比2种粉磨方式所得粉煤灰的粒度、比表面积、活性指数、球形颗粒余量、物相组成和化学组成等特性,以及2种粉磨方式的能耗与粉磨效率。结果表明:与球磨机相比,通过蒸汽动能磨所得的粉煤灰微粉的粒度更小,中位径达2.25μm,比表面积可达1 110.5 m2/kg,粉煤灰的活性指数更高,最高可达107.7%;蒸汽动能磨和球磨机不会改变粉煤灰的物相组成,但会降低粉煤灰中矿物结晶度;随粉磨强度的增加,粉煤灰粒度减小,晶体结晶度降低;粉磨破坏粉煤灰微珠颗粒,释放出内部Ca、 Si、 Al等成分,提升Si、 Al释放率,优化粉煤灰微粉的化学组成,强化水化反应;蒸汽动能磨的粉磨效率更高、耗能更少。

关键词:粉煤灰;球磨机;蒸汽动能磨;理化特性;粉磨效率

Abstract:In order to improve the comprehensive utilization efficiency of fly ash, a ball mill and a steam kinetic energy mill were used to grind fly ash. The particle size, specific surface area, activity index, remaining amount of spherical particles, phase composition and chemical composition of fly ash obtained by the two grinding methods were compared, as well as energy consumption and grinding efficiency of two grinding methods. The results show that compared with the ball mill, the particle size of fly ash powder obtained by steam kinetic energy grinding is smaller, the median diameter can reach 2.25 μm and the specific surface area can reach 1 110.5 m2/kg.The activity index of fly ash is higher and up to 107.7%. The phase composition of fly ash will not be changed and the crystallinity of minerals in fly ash will be reduced by steam kinetic energy mills and ball mills. As the grinding intensity increasing, the particle size is reduced and the crystallinity is reduced too. The grinding destroys the particles of fly ash and releases internal components such as Ca, Si and Al, which improves the release rate of Si and Al. The chemical composition of fly ash powder can be optimized and the hydration reaction can be strengthened.The steam kinetic energy mill has a higher grinding efficiency and a smaller energy consumption.

Keywords:fly ash; ball mill; steam kinetic energy mill; physicochemical properties; grinding efficiency


参考文献(References):

[1]JIN S X, ZHAO Z H, JIANG S F, et al.Comparison and summary of relevant standards for comprehensive utilization of fly ash at home and abroad[J].IOP Conference Series Earth and Environmental Science, 2021, 621(1): 012006.

[2]朱科明, 张馨圆, 王乐, 等.粉煤灰碱法提取氧化铝工艺研究进展[J].轻金属, 2019(9): 4-8.

[3]SIVAMANI S, SUJIT S.Optimization of synthesis parameters and characterization of coal fly ash derived microporous zeolite X[J].Applied Surface Science, 2018, 455: 903-910.

[4]XIAO X, QIN K, SUN X F, et al.Will wheat be damaged by heavy metals on exposure to coal fly ash[J].Atmospheric Pollution Research, 2018, 9(5): 814-821.

[5]孟宪彬, 李明君, 丁国光, 等.燃煤电厂粉煤灰综合利用分析[J].电力科技与环保, 2017, 33(4): 50-52.

[6]DU Y T, WANG H F, WANG Z C, et al.Mineralogical and active mechanical excitation characteristics of filled fly ash cementitious materials[J].Journal of Wuhan University of Technology(Materials Science), 2017, 32(2): 413-416.

[7]周立霞, 王起才.粉煤灰粒度分布及其活性的灰色关联分析[J].硅酸盐通报, 2011, 30(3): 656-661, 666.

[8]JIANG S Q, YE Y X, TAN Y Q, et al.Discrete element simulation of particle motion in ball mills based on similarity[J].Powder Technology, 2018, 335: 91-102.

[9]WANG M H, YANG R Y, YU A B.DEM investigation of energy distribution and particle breakage in tumbling ball mills[J].Powder Technology, 2012, 223: 83-91.

[10]吴彩斌.破碎统计力学原理及转移概率在装补球制度中的应用研究[D].昆明: 昆明理工大学, 2002.

[11]ZHAO J H, WANG D M, WANG X G, et al.Ultrafine grinding of fly ash with grinding aids: impact on particle characteristics of ultrafine fly ash and properties of blended cement containing ultrafine fly ash[J].Construction and Building Materials, 2015, 78: 250-259.

[12]ODAKA D, OHKI Y, MIZUNO M.Crystallinity of poly(ethylene naphthalate)and its relation to terahertz absorption[J].Japanese Journal of Applied Physics, 2017, 56(3): 032402.

[13]段思宇, 李溪, 马卓慧, 等.粉磨方式对钢渣微粉特性的影响[J].粉末冶金材料科学与工程, 2020, 25(1): 51-57.

[14]柯国军, 杨晓峰, 彭红, 等.化学激发粉煤灰活性机理研究进展[J].煤炭学报, 2005(3): 366-370.

[15]夏磊, 马军涛, 段爱萍, 等.粉煤灰粉磨后球形颗粒破坏度与活性的相关性分析[J].新型建筑材料, 2019, 46(8): 64-67.