张建峰a，王 宁a，刘 峰a，闵凡路b
（河海大学 a. 力学与材料学院；b. 土木与交通学院，江苏 南京 210000）
DOI：10.13732/j.issn.1008-5548.2023.02.002
收稿日期：2022-08-31，修回日期：2022-10-25，在线出版时间：2023-02-01 10:49。
基金项目：安徽省科技重大专项项目，编号：2021e03020005。
第一作者简介：张建峰(1978—)，男，教授，博士，博士生导师，研究方向为空心玻璃微珠强化及表面改性、耐磨材料开发。E-mail：jfzhang_sic@163.com。
摘要：综述空心玻璃微珠结构与发展历史，玻璃粉末法、喷雾造粒法、液滴法、干凝胶法、软化学法等空心玻璃微珠制备方法，在塑料、橡胶、树脂、乳化炸药、涂料、电磁屏蔽、微波吸收等方面的应用。提出空心玻璃微珠具备质量轻、强度高、流动性好，隔热、耐腐蚀等优点，在发展隔热、耐磨等复合材料中发挥越来越大的作用，在新能源产业和生物材料中的应用获得快速发展。认为在抗压强度、粒径等方面，空心玻璃微珠达不到高性能微珠的高强度和细粒径水准，微珠化学稳定性和精细化控制程度方面也有欠缺；在改进原料配方、优化生产工艺、提高后处理技术方面，以及针对全海深浮力材料、隔热涂料、乳化炸药等的应用方面应深入开展。
关键词：空心玻璃微珠；制备方法；生产现状；研究进展
Abstract：The structure and development history of hollow glass microbeads, preparation methods of hollow glass microbeads of glass powder method, spray granulation method, liquid drop method, dry gel method, and soft chemistry method, and the application of plastic, rubber, resin, emulsion explosive, coating, electromagnetic shielding and microwave absorption were summed. It is proposed that hollow glass beads have the advantages of light weight, high strength, good fluidity, heat insulation, corrosion resistance and so on. They are playing an increasing role in the development of heat insulation, wear resistance and other composite materials, and their applications in the new energy industry and biological materials are also developing rapidly. It is thought that In terms of compressive strength and particle size, hollow glass beads cannot reach the level of high strength and fine particle size of high performance beads, and the chemical stability and fine control degree of microbeads are also deficient. The studies of the improvement of raw material formula, optimization of production process, and improving post-treatment technology, as well as the whole sea deep buoyancy materials, heat insulation coating, and emulsion explosive applications should be further carried out.
Keywords：hollow glass microspheres; preparation method; production status; research progress
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